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class="title_bar"> 發布日期：<span>2018-01-04</span> 作者：<span></span> 點擊：<span><script src="http://www.bestbangkokvisarun.com/data/include/newshits.php?id=378"></script></span> </h3> <div class="share">  <div class="bdsharebuttonbox"> <a href="#" class="bds_more" data-cmd="more"></a> <a href="#" class="bds_qzone" data-cmd="qzone"></a> <a href="#" class="bds_tsina" data-cmd="tsina"></a> <a href="#" class="bds_tqq" data-cmd="tqq"></a> <a href="#" class="bds_renren" data-cmd="renren"></a> <a href="#" class="bds_weixin" data-cmd="weixin"></a> </div> <script> window._bd_share_config={"common":{"bdSnsKey":{},"bdText":"","bdMini":"2","bdPic":"","bdStyle":"0","bdSize":"16"},"share":{},"image":{"viewList":["qzone","tsina","tqq","renren","weixin"],"viewText":"分享到：","viewSize":"16"},"selectShare":{"bdContainerClass":null,"bdSelectMiniList":["qzone","tsina","tqq","renren","weixin"]}};with(document)0[(getElementsByTagName('head')[0]||body).appendChild(createElement('script')).src='http://bdimg.share.baidu.com/static/api/js/share.js?v=89860593.js?cdnversion='+~(-new Date()/36e5)]; </script>  </div> </div> <div class="content"><p style="line-height: 2em; text-indent: 2em;"><a href='http://www.bestbangkokvisarun.com/' target='_blank' class='key_tag'><font color=#2086ee><strong>貴州廢酸回收</strong></font></a>對廢酸回收系統凈化工段的說明解析</p><p style="line-height: 2em; text-indent: 2em;">廢酸回收系統可從廢酸中提取氯化亞鐵，同時獲得與原廢酸濃度相同的不含鐵鹽的純凈鹽酸，經配酸調整濃度重新投入酸洗中使用，做到零排放。廢酸回收系統分為好幾個工段，其中就有凈化工段，對這一工段的說明是：</p><p style="line-height: 2em; text-indent: 2em;">自凈化工段來的含SO2爐氣，補充一定量空氣，控制SO2濃度為~6.5%進入轉化器。氣體經干燥后所含水份達到0.1g/Nm3以下，進入二氧化硫鼓風機。干燥塔系填料塔，塔頂裝有金屬絲網除霧器。塔內用93%酸淋灑，吸水稀釋后自塔底流入干燥塔循環槽，槽內配入由吸收塔酸冷卻器出口串來的98%酸，以維持循環酸的濃度。然后經干燥塔循環泵打入干燥塔酸冷卻器冷卻后，進入干燥塔循環使用。增多的93%酸全部通過干燥塔循環泵串入一吸塔循環槽。</p><p style="line-height: 2em; text-indent: 2em;">經一次轉化后的氣體，溫度大約為180℃，進入一吸塔，吸收其中的SO3，經塔頂的纖維除霧器除霧后，返回轉化系統進行二次轉化。經二次轉化的轉化氣，溫度大約為156℃，進入二吸塔，吸收其中的SO3，經塔頂的纖維除霧器除霧后，再經過尾氣吸收塔進一步吸收殘余的SO2，Z后的尾氣通過煙囪達標排放。第一吸收塔和第二吸收塔均為填料塔，第一吸收塔和第二吸收塔各有一個酸循環槽，淋灑酸吸收SO3后的酸自塔底流入吸收塔循環槽混合，加水調節酸濃度，然后經吸收塔循環泵打入</p><p style="line-height: 2em; text-indent: 2em;">吸收塔酸冷卻器冷卻后，進入吸收塔循環使用。增多的硫酸，一部分串入干燥塔循環槽，一部分作為成品酸直接輸入成品酸貯罐。該成品酸再調配部分雜多酸和有機酸，作為烷基化反應過程的催化劑回用到烷基化反應單元。貴州廢酸回收</p><p style="line-height: 2em; text-indent: 2em;">廢酸中硫酸濃度較高，可經處理后回收再用。處理主要是去除廢硫酸中的雜質，同時對硫酸增濃。處理方法有濃縮法，是在加熱濃縮廢稀硫酸的過程中，使其中的有機物發生氧化、聚合等反應，轉變為深色膠狀物或懸浮物后過濾除去，從而達到去除雜質、濃縮稀硫酸的雙重目的。在普遍應用高溫濃縮法的基礎上又發展了較為先進的低溫濃縮法，下面分別加以介紹：</p><p style="line-height: 2em; text-indent: 2em;">1、高溫濃縮法</p><p style="line-height: 2em; text-indent: 2em;">三氯乙醛生產過程中有廢硫酸產生，其中H2SO4質量分數為65%～75%、三氯乙醛質量分數為1%～3%、其它有機雜質的質量分數為1%。該廠將其沉淀過濾后，用煤直接加熱蒸餾，回收的濃硫酸無色透明，H2SO4質量分數大于95%，無三氯乙醛檢出，而沉淀物經堿解、蒸餾和過濾后可回收氯仿。濃縮法是用搪玻璃管升膜蒸發和分段真空蒸發相結合，將廢硫酸中H2SO4的質量分數從10%～40%濃縮到95%，其工藝可分為3段，前兩段采用不透性石墨管加熱器蒸發濃縮，后一段采用搪玻璃管升膜蒸發器濃縮，在每一段中H2SO4質量分數漸次升高，分別達到60%、80%和95%。加熱過程采用高溫熱載體，溫度為150～220℃，可將有機物轉變為不溶性物質，然后過濾除去，該工藝以2t/h的規模進行中試，可用于含多種有機雜質的廢酸的處理。</p><p style="line-height: 2em; text-indent: 2em;">2、低溫濃縮法</p><p style="line-height: 2em; text-indent: 2em;">高溫濃縮法的缺點在于硫酸的強腐蝕性和酸霧對設備和操作人員的危害很大，實際操作非常麻煩。因此，近年來開發出了一種改進的濃縮法，貴州廢酸回收稱為汽液分離型非揮發性溶液濃縮法(簡稱WCG法)。</p><p style="text-align: center;"><img src="/data/upload/image/20180104/1515047826413609.jpg" title="貴州廢酸回收" alt="貴州廢酸回收" width="650" height="514" border="0" vspace="0" style="width: 650px; height: 514px;"/></p><p><br/></p><p>(本文內容來源于網絡，如有侵權請聯系刪除)</p></div> <h3 class="tag">本文網址：http://www.bestbangkokvisarun.com/news/378.html </h3> <h3 class="tag">相關標簽：<a 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